The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In the case already considered, as in the case of formic acid
in the researches of D. P. Konovaloff (note 47), the constant
boiling solution corresponds with a minimum tension--that
is, with a boiling point higher than that of either of the
component elements. But there is another case of constant boiling
solutions similar to the case of the solution of propyl alcohol,
C_{3}H_{8}O, when a solution, undecomposed by distillation, boils
at a lower point than that of the more volatile liquid. However,
in this case also, if there be solution, the possibility of the
formation of a definite compound in the form C_{3}H_{8}O + H_{2}O
cannot be denied, and the tension of the solution is not equal to
the sum of tensions of the components. There are possible cases
of constant boiling mixtures even when there is no solution nor
any loss of tension, and consequently no chemical action, since
the amount of liquids that are volatilised is determined by
the product of the vapour densities into their vapour tensions
(Wanklyn), in consequence of which liquids whose boiling point
is above 100°--for instance, turpentine and ethereal oils in
general--when distilled with aqueous vapour, pass over at a
temperature below 100°. Consequently, it is not in the constancy
of composition and boiling point (temperature of decomposition)
that evidence of a distinct chemical action is to be found in
the above-described solutions of acids, but in the great loss
of tension, which completely resembles the loss of tension
observed, for instance, in the perfectly-definite combinations of
substances with water of crystallisation (see later, note 65).
Sulphuric acid, H_{2}SO_{4}, as we shall learn later, is also
decomposed by distillation, like HCl + 6H_{2}O, and exhibits,
moreover, all the signs of a definite chemical compound. The
study of the variation of the specific gravities of solutions as
dependent on their composition (see note 19) shows that phenomena
of a similar kind, although of different dimensions, take place
in the formation of both H_{2}SO_{4} from H_{2}O and SO_{3}, and
of HCl + 6H_{2}O (or of aqueous solutions analogous to it) from
HCl and H_{2}O.
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