The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
manner.[64] The tension of the aqueous vapour which is given off
from crystallo-hydrates is naturally, as with solutions, less than
the vapour tension of water itself[65] at the same temperature, and
therefore many anhydrous salts which are capable of combining with
water absorb aqueous vapour from moist air; that is, they act like a
cold body on which water is deposited from steam. It is on this that
the desiccation of gases is based, and it must further be remarked in
this respect that certain substances--for instance, potassium carbonate
(K_{2}CO_{3}) and calcium chloride (CaCl_{2})--not only absorb the water
necessary for the formation of a solid crystalline compound, but also
give solutions, or _deliquesce_, as it is termed, in moist air. Many
crystals do not effloresce in the least at the ordinary temperature;
for example, copper sulphate, which may be preserved for an indefinite
length of time without efflorescing, but when placed under the receiver
of an air pump, if efflorescence be once started, it goes on at the
ordinary temperature. The temperature at which the complete separation
of water from crystals takes place varies considerably, not only for
different substances, but also for different portions of the contained
water. Very often the temperature at which dissociation begins is very
much higher than the boiling point of water. So, for example, copper
sulphate, which contains 36 p.c. of water, gives up 28·8 p.c. at 100°,
and the remaining quantity, namely 7·2 p.c., only at 240°. Alum, out of
the 45·5 p.c. of water which it contains, gives up 18·9 p.c. at 100°,
17·7 p.c. at 120°, 7·7 p.c. at 180°, and 1 p.c. at 280°; it only loses
the last quantity (1 p.c.) at its temperature of decomposition. These
examples clearly show that the annexation of water of crystallisation
is accompanied by a rather profound, although, in comparison with
instances which we shall consider later, still inconsiderable, change
of its properties. In certain cases the water of crystallisation is
only given off when the solid form of the substance is destroyed: when
the crystals melt on heating. The crystals are then said _to melt in
their water of crystallisation_. Further, after the separation of the
water, a solid substance remains behind, so that by further heating it
acquires a solid form. This is seen most clearly in crystals of sugar of
lead or lead acetate, which melt in their water of crystallisation at a
temperature of 56·25°, and in so doing begin to lose water. On reaching
a temperature of 100° the sugar of lead solidifies, having lost all its
water; and then at a temperature of 280°, the anhydrous and solidified
salt again melts.[65 bis]
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