The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
(or H_{4}SO_{5}), appear as true definite chemical compounds. If,
then, we imagine such a definite compound in a liquid state, and admit
that it partially decomposes in this state, separating water--not as
ice or vapour (for then the system would be heterogeneous, including
substances in different physical states), but in a liquid form, when
the system will be homogeneous--we shall form an idea of a solution as
an unstable, dissociating fluid state of equilibrium between water and
the substance dissolved. Moreover, it should be remarked that, judging
by experiment, many substances give with water not one but _diverse_
compounds,[67] which is seen in the capacity of one substance to form
with water many various _crystallo-hydrates_, or compounds with water
of crystallisation, showing diverse and independent properties. From
these considerations, _solutions[68] may be regarded as fluid, unstable,
definite chemical compounds in a state of dissociation_.[69]
[66] Such a phenomenon frequently presents itself in purely chemical
action. For instance, let a liquid substance _A_ give, with
another liquid substance _B_, under the conditions of an
experiment, a mere minute quantity of a solid or gaseous
substance _C_. This small quantity will separate out (pass
away from the sphere of action, as Berthollet expressed it),
and the remaining masses of _A_ and _B_ will again give _C_;
consequently, under these conditions action will go on to the
end. Such, it seems to me, is the action in solutions when they
yield ice or vapour indicating the presence of water.
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