The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
A wide porcelain tube P (fig. 19) is placed in a furnace, which can be
raised to a high temperature (it should be heated with small pieces of
good coke). In this tube there is inserted a second tube T, of smaller
diameter, made of unglazed earthenware and therefore porous. The ends
of the tube are luted to the wide tube, and two tubes, C and C', are
inserted into the ends, as shown in the drawing. With this arrangement
it is possible for a gas to pass into the annular space between the
walls of the two tubes, from whence it can be collected. Steam from a
retort or flask is passed through the tube D, into the inner porous
tube T. This steam on entering the red-hot space is decomposed into
hydrogen and oxygen. The densities of these gases are very different,
hydrogen being sixteen times lighter than oxygen. Light gases, as we
saw above, penetrate through porous surfaces very much more rapidly
than denser gases, and therefore the hydrogen passes through the
pores of the tube into the annular space very much more rapidly than
the oxygen. The hydrogen which separates out into the annular space
can only be collected when this space does not contain any oxygen.
If any air remains in this space, then the hydrogen which separates
out will combine with its oxygen and form water. For this reason a
gas incapable of supporting combustion--for instance, nitrogen or
carbonic anhydride--is previously passed into the annular space. Thus
the carbonic anhydride is passed through the tube C, and the hydrogen,
separated from the steam, is collected through the tube C', and will be
partly mixed with carbonic anhydride. A certain portion of the carbonic
anhydride will penetrate through the pores of the unglazed tube into
the interior of the tube T. The oxygen will remain in this tube, and
the volume of the remaining oxygen will be half that of the volume of
hydrogen which separates out from the annular space.[6 bis]
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