The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Na_{2}O + H (both with the aid of heat)--consequently, in this
case heat is absorbed. In this we see an example of calorimetric
calculations and the limited application of the law of maximum
work for the general phenomena of reversible reactions, to which
the case just considered belongs. But it must be remarked that
all reversible reactions evolve or absorb but little heat, and
the reason of the law of maximum work, not being universal must
first of all be looked for in the fact that we have no means of
separating the heat which corresponds with the purely chemical
process from the sum total of the heat observed, and as the
structure of a number of substances is altered by heat and also
by contact, we can scarcely hope that the time approaches when
such a distinction will be possible. A heated substance, in point
of fact, has no longer the original energy of its atoms--that is,
the act of heating not only alters the store of motion of the
molecules but also of the atoms forming the molecules, in other
words, it makes the beginning of or preparation for chemical
change. From this it must be concluded that thermochemistry, or
the study of the heat accompanying chemical transformations,
cannot he identified with chemical mechanics. Thermo-chemical data
form a part of it, but they alone cannot give it.
Sodium and potassium act on water at the ordinary temperature. Other
heavier metals only act on it with a rise of temperature, and then not
so rapidly or vigorously. Thus magnesium and calcium only liberate
hydrogen from water at its boiling point, and zinc and iron only a red
heat, whilst a whole series of heavy metals, such as copper, lead,
mercury, silver, gold, and platinum, do not in the least decompose water
at any temperature, and do not replace its hydrogen.
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