The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
in the sulphuric acid and forms zinc sulphate, which remains in
solution, and therefore the hydrogen generated will be quite free
from oxygen.
[22] An inverted beaker is attached to one arm of the beam of a
tolerably sensitive balance, and its weight counterpoised by
weights in the pan attached to the other arm, If the beaker
be then filled with hydrogen it rises, owing to the air being
replaced by hydrogen. Thus, at the ordinary temperature of a
room, a litre of air weighs about 1·2 gram, and on replacing the
air by hydrogen a decrease in weight of about 1 gram per litre is
obtained. Moist hydrogen is heavier than dry--for aqueous vapour
is nine times heavier than hydrogen. In filling balloons it is
usually calculated that (it being impossible to have perfectly
dry hydrogen or to obtain it quite free from air) the lifting
force due to the difference between the weights of equal volumes
of hydrogen and air is equal to 1 kilogram (= 1,000 grams) per
cubic metre (= 1,000 litres).
[23] The density of hydrogen in relation to the air has been repeatedly
determined by accurate experiments. The first determination, made
by Lavoisier, was not very exact; taking the density of air as
unity, he obtained 0·0769 for that of hydrogen--that is, hydrogen
as thirteen times lighter than air. More accurate determinations
are due to Thomsen, who obtained the figure 0·0693; Berzelius
and Dulong, who obtained 0·0688; and Dumas and Boussingault, who
obtained 0·06945. Regnault, and more recently Le Duc (1892),
took two spheres of considerable capacity, which contained equal
volumes of air (thus avoiding the necessity of any correction
for weighing them in air). Both spheres were attached to the
scale pans of a balance. One was sealed up, and the other first
weighed empty and then full of hydrogen. Thus, knowing the weight
of the hydrogen filling the sphere, and the capacity of the
sphere, it was easy to find the weight of a litre of hydrogen;
and, knowing the weight of a litre of air at the same temperature
and pressure, it was easy to calculate the density of hydrogen.
Regnault, by these experiments, found the average density of
hydrogen to be 0·06926 in relation to air; Le Duc, 0·06948 (with
a possible error of ±0·00001), and this latter figure must now be
looked upon as near to the truth.
In this work I shall always refer the densities of all gases to
hydrogen, and not to air; I will therefore give, for the sake of
clearness, the weight of a litre of dry pure hydrogen in grams
at a temperature _t_° and under a pressure _H_ (measured in
millimetres of mercury at 0°, in lat. 45°). The weight of a litre
of hydrogen
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account