The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[33] The investigations of S. Wroblewski in Cracow give reason to
believe that Pictet could not have obtained liquid hydrogen in
the interior of his apparatus, and that if he did obtain it,
it could only have been at the moment of its outrush due to
the fall in temperature following its sudden expansion. Pictet
calculated that he obtained a temperature of -140°, but in reality
it hardly fell below -120°, judging from the latest data for
the vaporisation of carbonic anhydride under low pressure. The
difference lies in the method of determining low temperatures.
Judging from other properties of hydrogen (_see_ Note 34), one
would think that its absolute boiling point lies far below -120°,
and even -140° (according to the calculation of Sarrau, on the
basis of its compressibility, at -174°). But even at -200° (if the
methods of determining such low temperatures be correct) hydrogen
does not give a liquid even under a pressure of several hundred
atmospheres. However, on expansion a fog is formed and a liquid
state attained, but the liquid does not separate.
[34] After the idea of the absolute temperature of ebullition (_tc_,
Note 29) had been worked out (about 1870), and its connection
with the deviations from Mariotte's law had become evident, and
especially after the liquefaction of permanent gases, general
attention was turned to the development of the fundamental
conceptions of the gaseous and liquid states of matter. Some
investigators directed their energies to the further study of
vapours (for instance, Ramsay and Young), gases (Amagat), and
liquids (Zaencheffsky, Nadeschdin, and others), especially to
liquids near _tc_ and _pc_; others (Konovaloff and De Heen)
endeavoured to discover the relation between liquids under
ordinary conditions (removed from _tc_ and _pc_) and gases,
whilst a third class of investigators (van der Waals, Clausius,
and others), starting from the generally-accepted principles
of the mechanical theory of heat and the kinetic theory of
gases, and assuming in gases the existence of those forces which
certainly act in liquids, deduced the connection between the
properties of one and the other. It would be out of place in
an elementary handbook like the present to enunciate the whole
mass of conclusions arrived at by this method, but it is well to
give an idea of the results of van der Waals' considerations,
for they explain the gradual uninterrupted passage from a liquid
into a gaseous state in the simplest manner, and, although the
deduction cannot be considered as complete and decisive (_see_
Note 25), nevertheless it penetrates so deeply into the essence
of the matter that its signification is not only reflected in a
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