The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[5] The extraction of oxygen from water may be effected by two
processes: either by the decomposition of water into its
constituent parts by the action of a galvanic current (Chapter
II.), or by means of the removal of the hydrogen from water.
But, as we have seen and already know, hydrogen enters into
direct combination with very few substances, and then only under
special circumstances; whilst oxygen, as we shall soon learn,
combines with nearly all substances. Only gaseous chlorine (and,
especially, fluorine) is capable of decomposing water, taking up
the hydrogen from it, without combining with the oxygen. Chlorine
is soluble in water, and if an aqueous solution of chlorine,
so-called chlorine water, be poured into a flask, and this flask
be inverted in a basin containing the same chlorine water, then we
shall have an apparatus by means of which oxygen may be extracted
from water. At the ordinary temperature, and in the dark, chlorine
does not act on water, or only acts very feebly; but under the
action of direct sunlight chlorine decomposes water, with the
evolution of oxygen. The chlorine then combines with the hydrogen,
and gives hydrochloric acid, which dissolves in the water, and
therefore free oxygen only will be separated from the liquid, and
it will only contain a small quantity of chlorine in admixture,
which can be easily removed by passing the gas through a solution
of caustic potash.
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