The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Graham, however, succeeded in enriching air in oxygen by passing
it through india-rubber. This may be done in the following
way:--A common india-rubber cushion, E (Fig. 27), is taken, and
its orifice hermetically connected with an air-pump, or, better
still, a mercury aspirator (the Sprengel pump is designated by
the letters A, C, B). When the aspirator (Chapter II., Note 16)
has pumped out the air, which will be seen by the mercury running
out in an almost uninterrupted stream, and from its standing
approximately at the barometric height, then it may be clearly
observed that gas passes through the india-rubber. This is also
seen from the fact that bubbles of gas continually pass along
with the mercury. A minus pressure may be constantly maintained
in the cushion by pouring mercury into the funnel A, and screwing
up the pinchcock C, so that the stream flowing from it is small,
and then a portion of the air passing through the india-rubber
will be carried along with the mercury. This air may be collected
in the cylinder, R. Its composition proves to be about 42 volumes
of oxygen with 57 volumes of nitrogen, and one volume of carbonic
anhydride, whilst ordinary air contains only 21 volumes of oxygen
in 100 volumes. A square metre of india-rubber surface (of the
usual thickness) passes about 45 c.c. of such air per hour. This
experiment clearly shows that india-rubber is permeable to gases.
This may, by the way, be observed in common toy balloons filled
with coal-gas. They fall after a day or two, not because there
are holes in them, but because air penetrates into, and the gas
from, their interior, through the surface of the india-rubber of
which they are made. The rate of the passage of gases through
india-rubber does not, as Mitchell and Graham showed, depend
on their densities, and consequently its permeability is not
determined by orifices. It more resembles dialysis--that is, the
penetration of liquids through colloid surfaces. Equal volumes
of gases penetrate through india-rubber in periods of time which
are related to each other as follows:--carbonic anhydride, 100;
hydrogen, 247; oxygen, 532; marsh gas, 633; carbonic oxide,
1,220; nitrogen, 1,358. Hence nitrogen penetrates more slowly
than oxygen, and carbonic anhydride more quickly than other
gases. 2·556 volumes of oxygen and 13·585 volumes of carbonic
anhydride penetrate in the same time as one volume of nitrogen.
By multiplying these ratios by the amounts of these gases in air,
we obtain figures which are in almost the same proportion as the
volumes of the gases penetrating from air through india-rubber. If
the process of dialysis be repeated on the air which has already
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