The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[8] Even the decomposition of manganese peroxide is reversible, and it
may be re-obtained from that suboxide (or its salts), which
is formed in the evolution of oxygen (Chap. XI., Note 6). The
compounds of chromic acid containing the trioxide CrO_{3} in
evolving oxygen give chromium oxide, Cr_{2}O_{3}, but they re-form
the salt of chromic acid when heated to redness in air with an
alkali.
1. _The compounds of oxygen_ with certain metals, and especially
with the so-called noble metals--that is, mercury, silver, gold, and
platinum--having once been obtained, retain their oxygen at the ordinary
temperature, but part with it at a red heat. The compounds are solids,
generally amorphous and infusible, and are easily decomposed by heat
into the metal and oxygen. We have seen an example of this in speaking
of the decomposition of mercury oxide. Priestley, in 1774, obtained
pure oxygen for the first time by heating mercury oxide by means of a
burning-glass, and clearly showed its difference from air. He showed
its characteristic property of supporting combustion 'with remarkable
vigour,' and named it dephlogisticated air.
2. The substances called _peroxides_[9] evolve oxygen at a greater or
less heat (and also by the action of many acids). They usually contain
metals combined with a large quantity of oxygen. Peroxides are the
highest oxides of certain metals; those metals which form them generally
give several compounds with oxygen. Those of the lowest degrees of
oxidation, containing the least amount of oxygen, are generally
substances which are capable of easily reacting with acids--for
instance, with sulphuric acid. Such low oxides are called bases.
Peroxides contain more oxygen than the bases formed by the same metals.
For example, lead oxide contains 7·1 parts of oxygen in 100 parts, and
is basic, but lead peroxide contains 13·3 parts of oxygen in 100 parts.
_Manganese peroxide_ is a similar substance, and is a solid of a dark
colour, which occurs in nature. It is employed for technical purposes
under the name of black oxide of manganese (in German, 'Braunstein,' the
pyrolusite of the mineralogist). Peroxides are able to evolve oxygen
at a more or less elevated temperature. They do not then part with all
their oxygen, but with only a portion of it, and are converted into
a lower oxide or base. Thus, for example, lead peroxide, on heating,
gives oxygen and lead oxide. The decomposition of this peroxide proceeds
tolerably easily on heating, even in a glass vessel, but manganese
peroxide only evolves oxygen at a strong red heat, and therefore oxygen
can only be obtained from it in iron, or other metallic, or clay
vessels. This was formerly the method for obtaining oxygen. Manganese
peroxide only parts with one-third of its oxygen (according to the
equation 3MnO_{2} = Mn_{3}O_{4} + O_{2}), whilst two-thirds remain in
the solid substance which forms the residue after heating. Metallic
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