The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
3. A third source to which recourse may be had for obtaining oxygen is
represented in _acids_ and _salts_ containing much oxygen, which are
capable, by parting with a portion or all of their oxygen, of being
converted into other compounds (lower products of oxidation) which are
more difficultly decomposed. These acids and salts (like peroxides)
evolve oxygen either on heating alone, or only when in the presence
of some other substance. Sulphuric acid may be taken as an example of
an acid which is decomposed by the action of heat alone,[11] for it
breaks up at a red heat into water, sulphurous anhydride, and oxygen,
as was mentioned before. Priestley, in 1772, and Scheele, somewhat
later, obtained oxygen by heating nitre to a red heat. The best
examples of the formation of oxygen by the heating of salts is given
in _potassium chlorate_, or Berthollet's salt, so called after the
French chemist who discovered it. Potassium chlorate is a salt composed
of the elements potassium, chlorine, and oxygen, KClO_{3}. It occurs
as transparent colourless plates, is soluble in water, especially in
hot water, and resembles common table salt in some of its reactions
and physical properties; it melts on heating, and in melting begins
to decompose, evolving oxygen gas. This decomposition ends in all the
oxygen being evolved from the potassium chlorate, potassium chloride
being left as a residue, according to the equation KClO_{3} = KCl +
O_{3}.[12] This decomposition proceeds at a temperature which allows
of its being conducted in a glass vessel. However, in decomposing,
the molten potassium chlorate swells up and boils, and gradually
solidifies, so the evolution of the oxygen is not regular, and the
glass vessel may crack. In order to overcome this inconvenience, the
potassium chlorate is crushed and mixed with a powder of a substance
which is infusible, incapable of combining with the oxygen evolved,
and is a good conductor of heat. Usually it is mixed with manganese
peroxide.[13] The decomposition of the potassium chlorate is then
considerably facilitated, and proceeds at a lower temperature (because
the entire mass is then better heated, both externally and internally),
without swelling up, and this method is therefore more convenient than
the decomposition of the salt alone. This method for the preparation
of oxygen is very convenient; it is generally employed when a small
quantity of oxygen is required. Further, potassium chlorate is easily
obtained pure, and it evolves much oxygen. 100 grams of the salt give as
much as 39 grams, or 30 litres, of oxygen. This method is so simple and
easy,[14] that a course of practical chemistry is often commenced by the
preparation of oxygen by this method, and of hydrogen by the aid of zinc
and sulphuric acid, since by means of these gases many interesting and
striking experiments may be performed.[15]
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