The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
A solution of _bleaching powder_, which contains calcium hypochlorite,
CaCl_{2}O_{2}, evolves oxygen on gently heating when a small quantity
of certain oxides is added--for instance, cobalt oxide, which in this
case acts by contact (_see_ Introduction). When heated by itself, a
solution of bleaching powder does not evolve oxygen, but it oxidises
the cobalt oxide to a higher degree of oxidation; this higher oxide of
cobalt in contact with the bleaching powder decomposes into oxygen and
lower oxidation products, and the resultant lower oxide of cobalt with
bleaching powder again gives the higher oxide, which again gives up
its oxygen, and so on.[16] The calcium hypochlorite is here decomposed
according to the equation CaCl_{2}O_{2} = CaCl_{2} + O_{2}. In this
manner a small quantity of cobalt oxide[17] is sufficient for the
decomposition of an indefinitely large quantity of bleaching powder.
[16] Such is, at present, the only possible method of explaining the
phenomenon of contact action. In many cases, such as the present
one, it is supported by observations based on facts. Thus,
for instance, it is known, as regards oxygen, that often two
substances rich in oxygen retain it so long as they are separate,
but directly they come into contact free oxygen is evolved from
both of them. Thus, an aqueous solution of hydrogen peroxide
(containing twice as much oxygen as water) acts in this manner on
silver oxide (containing silver and oxygen). This reaction takes
place at the ordinary temperature, and the oxygen is evolved
from both compounds. To this class of phenomena may be also
referred the fact that a mixture of barium peroxide and potassium
manganate with water and sulphuric acid evolves oxygen at the
ordinary temperature (Note 9 bis). It would seem that the essence
of phenomena of this kind is entirely and purely a property of
contact; the distribution of the atoms is changed by contact,
and if the equilibrium be unstable it is destroyed. This is more
especially evident in the case of those substances which change
exothermally--that is, for those reactions which are accompanied
by an evolution of heat. The decomposition CaCl_{2}O_{2} =
CaCl_{2} + O_{2} belongs to this class (like the decomposition of
potassium chlorate).
[17] Generally a solution of bleaching powder is alkaline (contains
free lime), and therefore, a solution of cobalt chloride is added
directly to it, by which means the oxide of cobalt required for
the reaction is formed.
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