The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[46] In _flames_ the separate parts may be distinguished with more or
less distinctness. That portion of the flame whither the
combustible vapours or gases flow, is not luminous because its
temperature is still too low for the process of combustion to
take place in it. This is the space which in a candle surrounds
the wick, or in a gas jet is immediately above the orifice from
which the gas escapes. In a candle the combustible vapours and
gases which are formed by the action of heat on the melted
tallow or stearin rise in the wick, and are heated by the high
temperature of the flame. By the action of the heat, the solid or
liquid substance is here, as in other cases, decomposed, forming
products of dry distillation. These products occur in the central
portion of the flame of a candle. The air travels to it from the
outside, and is not able to intermix at once with the vapours
and gases in all parts of the flame equally; consequently, in
the outer portion of the flame the amount of oxygen will be
greater than in the interior portions. But, owing to diffusion,
the oxygen, of course mixed with nitrogen, flowing towards the
combustible substance, does finally penetrate to the interior
of the flame (when the combustion takes place in ordinary air).
The combustible vapours and gases combine with this oxygen,
evolve a considerable amount of heat, and bring about that state
of incandescence which is so necessary both for keeping up the
combustion and also for the uses to which the flame is applied.
Passing from the colder envelope of air through the interior
of the flame, to the source of the combustible vapours (for
instance, the wick), we evidently first traverse layers of higher
and higher temperature, and then portions which are less and
less hot, in which the combustion is less complete, owing to the
limited supply of oxygen.
[Illustrationtion: FIG. 36.--In the candle flame the portion C
contains the vapours and products of decomposition; in the bright
zone A the combustion has commenced, and particles of carbon are
emitted; and in the pale zone B the combustion is completed.]
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