The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Salts belong to the class of substances which have been known
since very early times, and have long been investigated in many
directions. At first, however, no distinction was made between
salts, acids, and bases. Glauber prepared many artificial salts
during the latter half of the seventeenth century. Up to that
time the majority of salts were obtained from natural sources,
and that salt which we have referred to several times--namely,
sodium sulphate--was named Glauber's salt after this chemist.
Rouelle distinguished normal, acid, and basic salts, and showed
their action on vegetable dyes, still he confounded many salts
with acids (even now every acid salt ought to be regarded as an
acid, because it contains hydrogen, which may be replaced by
metals--that is, it is the hydrogen of an acid). Baumé disputed
Rouelle's opinion concerning the subdivision of salts, contending
that normal salts only are true salts, and that basic salts are
simple mixtures of normal salts with bases and acid salts with
acids, considering that washing alone could remove the base or
acid from them. Rouelle, in the middle of the last century,
however, rendered a great service to the study of salts and the
diffusion of knowledge respecting this class of compounds in
his attractive lectures. He, like the majority of the chemists
of that period, did not employ the balance in his researches,
but satisfied himself with purely qualitative data. The first
quantitative researches on salts were carried on about this
time by Wenzel, who was the director of the Freiburg mines, in
Saxony. Wenzel studied the double decomposition of salts, and
observed that in the double decomposition of neutral salts a
neutral salt was always obtained. He proved, by a method of
weighing, that this is due to the fact that the saturation of a
given quantity of a base requires such relative quantities of
different acids as are capable of saturating every other base.
Having taken two neutral salts--for example, sodium sulphate and
calcium nitrate--let us mix their solutions together. Double
decomposition takes place, because calcium sulphate is formed,
which is almost insoluble. However much we might add of each
of the salts, the neutral reaction will still be preserved,
consequently the neutral character of the salts is not destroyed
by the interchange of metals; that is to say, that quantity of
sulphuric acid which saturated the sodium is sufficient for the
saturation of the calcium, and that amount of nitric acid which
saturated the calcium is enough to saturate the sodium contained
in combination with sulphuric acid in sodium sulphate. Wenzel
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