The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[31] I consider that in an elementary text-book of chemistry, like the
present, it is only possible and advisable to mention, in
reference to chemical mechanics, a few general ideas and some
particular examples referring more especially to gases, whose
mechanical theory must be regarded as the most complete. The
molecular mechanics of liquids and solids is as yet in embryo,
and contains much that is disputable; for this reason, chemical
mechanics has made less progress in relation to these substances.
It may not be superfluous here to remark, with respect to the
conception of chemical affinity, that up to the present time
gravity, electricity, and heat have all been applied to its
elucidation. Efforts have also been made to introduce the
luminiferous ether into theoretical chemistry, and should that
connection between the phenomena of light and electricity
which was established by Maxwell be worked out more in detail,
doubtless these efforts to elucidate all or a great deal by
the aid of luminiferous ether will again appear in theoretical
chemistry. An independent chemical mechanics of the material
particles of matter, and of their internal (atomic) changes,
would, in my opinion, arise as the result of these efforts.
Two hundred years ago Newton laid the foundation of a truly
scientific theoretical mechanics of external visible motion, and
on this foundation erected the edifice of celestial mechanics.
One hundred years ago Lavoisier arrived at the first fundamental
law of the internal mechanics of invisible particles of matter.
This subject is far from having been developed into a harmonious
whole, because it is much more difficult, and, although many
details have been completely investigated, it does not possess
any starting points. Newton only came after Copernicus and
Kepler, who had discovered empirically the exterior simplicity
of celestial phenomena. Lavoisier and Dalton may, in respect to
the chemical mechanics of the molecular world, be compared to
Copernicus and Kepler. But a Newton has not yet appeared in the
molecular world; when he does, I think that he will find the
fundamental laws of the mechanics of the invisible motions of
matter more easily and more quickly in the chemical structure
of matter than in physical phenomena (of electricity, heat,
and light); for these latter are accomplished by particles of
matter already arranged, whilst it is now clear that the problem
of chemical mechanics mainly lies in the apprehension of those
motions which are invisibly accomplished by the smallest atoms of
matter.
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