The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
As the chemical changes to which substances are liable proceed from
internal forces proper to these substances, as chemical phenomena
certainly consist of motions of material parts (from the laws
of the indestructibility of matter and of elements), and as the
investigation of mechanical and physical phenomena proves the law of
the _indestructibility of forces_, or the conservation of energy--that
is, the possibility of the transformation of one kind of motion into
another (of visible or mechanical into invisible or physical)--we are
inevitably obliged to acknowledge the presence in substances (and
especially in the elements of which all others are composed) of a store
of _chemical energy_ or invisible motion inducing them to enter into
combinations. If heat be evolved in a reaction, it means that a portion
of chemical energy is transformed into heat;[32] if heat be absorbed
in a reaction,[33] that it is partly transformed (rendered latent) into
chemical energy. The store of force or energy going to the formation
of new compounds may, after several combinations, accomplished with an
absorption of heat, at last diminish to such a degree that indifferent
compounds will be obtained, although these sometimes, by combining with
energetic elements or compounds, give more complex compounds, which
may be capable of entering into chemical combination. Among elements,
gold, platinum, and nitrogen have but little energy, whilst potassium,
oxygen, and chlorine have a very marked degree of energy. When
dissimilar substances enter into combination they often form substances
of diminished energy. Thus sulphur and potassium when heated easily burn
in air, but when combined together their compound is neither inflammable
nor burns in air like its component parts. Part of the energy of the
potassium and of the sulphur was evolved in their combination in the
form of heat. Just as in the passage of substances from one physical
state into another a portion of their store of heat is absorbed or
evolved, so in combinations or decompositions and in every chemical
process, there occurs a change in the store of chemical energy, and at
the same time an evolution or absorption of heat.[34]
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