The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
At the present day it may be asserted upon the basis of existing data,
respecting the action of high temperature, that all compound bodies are
decomposed at a more or less high temperature. We have already seen
examples of this in describing the decomposition of mercury oxide into
mercury and oxygen, and the decomposition of wood under the influence
of heat. Many substances are decomposed at a very moderate temperature;
for instance, the fulminating salt which is employed in cartridges is
decomposed at a little above 120°. The majority of those compounds
which make up the mass of animal and vegetable tissues are decomposed
at 200°. On the other hand, there is reason to think that at a very
low temperature no reaction whatever can take place. Thus plants cease
to carry on their chemical processes during the winter. Raoul Pictet
(1892), employing the very low temperatures (as low as -200°C.) obtained
by the evaporation of liquefied gases (_see_ Chap. II.), has recently
again proved that at temperatures below -120°, even such reactions as
those between sulphuric acid and caustic soda or metallic sodium do not
take place, and even the coloration of litmus by acids only commences
at temperatures above -80°. If a given reaction does not take place at
a certain low temperature, it will at first only proceed slowly with
a rise of temperature (even if aided by an electric discharge), and
will only proceed rapidly, with the evolution of heat, when a certain
definite temperature has been reached. Every chemical reaction requires
certain limits of temperature for its accomplishment, and, doubtless,
many of the chemical changes observed by us cannot take place in the
sun, where the temperature is very high, or on the moon, where it is
very low.
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