The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[22] These coloured precipitates of alumina are termed _lakes_, and are
employed in dyeing tissues and in the formation of various
pigments--such as pastels, oil colours, &c. Thus, if organic
colouring matters, such as logwood, madder, &c., are added to a
solution of any aluminium salt, and then an alkali is added, so
that alumina may be precipitated, these pigments, which are by
themselves soluble in water, will come down with the precipitate.
This shows that alumina is able to combine with the colouring
matter, and that this compound is not decomposed by water. The
dyes then become insoluble in water. If a dye be mixed with starch
paste and aluminium acetate, and then, by means of engraved blocks
having a design in relief, we transfer this mixture to a fabric
which is then heated, the aluminium acetate will leave the
hydrogel of alumina which binds the colouring matter, and water
will no longer be able to wash the pigment from the material--that
is, a so-called 'fixed' dye is obtained. In the case of dyeing a
fabric a uniform tint, it is first soaked in a solution of
aluminium acetate and then dried, by which means the acetic acid
is driven off, while the hydrogel of alumina adheres to the fibres
of the material. If the latter be then passed through a solution
of a dye in water, the former will be attracted to the portions
covered with alumina, and closely adhere to them. If certain parts
of the material be protected by the application of an acid, such
as tartaric, C_{4}H_{6}O_{6}, oxalic, citric, &c. (these acids
being non-volatile), the alumina will be dissolved in those parts,
and the pigment will not adhere, so that after washing, a white
design will be obtained on those parts which have been so
protected.
In dye-works the aluminium acetate is generally obtained in
solution by taking a solution of alum, and mixing it with a
solution of lead acetate. In this case lead sulphate is
precipitated and aluminium acetate remains in solution, together
with either acetate or sulphate of potassium, according to the
amount of acetate of lead first taken. The complete decomposition
will be as follows: KAl(SO_{4})_{2} + 2Pb(C_{2}H_{3}O_{2})_{2} =
KC_{2}H_{3}O_{2} + Al(C_{2}H_{3}O_{2})_{3} + 2PbSO_{4}, or the
less complete decomposition, 2KAl(SO_{4})_{2} +
3Pb(C_{2}H_{3}O_{2})_{2} = 2Al(C_{2}H_{3}O_{2})_{3} + K_{2}SO_{4}
+ 3PbSO_{4}. If the resultant solution of aluminium acetate be
evaporated or further boiled, the acetic acid passes off and the
hydrogel of alumina remains.
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