The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[29] As the colloidal properties are particularly sharply developed in
those oxides (Al_{2}O_{3}, SiO_{2}, MoO_{3}, SnO_{2}, &c.) which
show (like water also) the properties of feeble bases and feeble
acids, there is probably some causal reason for this coincidence,
all the more so since among organic substances--gelatins,
albumins, &c.--the representatives of the colloids also have the
property of feebly combining with bases and acids.
[30] Since Deville's experiments the question of the density of
aluminium chloride has been frequently re-investigated. The
subject has more especially occupied the attention of Nilson,
Pettersson, Friedel and Crafts, and V. Meyer and his
collaborators. In general, it has been found that at low
temperatures (up to 440°) the density is constant, and indicates a
molecule Al_{2}Cl_{6}; whilst depolymerisation probably (although
it is not yet certain) takes place at higher temperatures, and the
molecule AlCl_{3} is obtained. Along with this there has been, and
still is, a difference of opinion as to the vapour density of
aluminium ethyl and methyl--whether for instance, Al(CH_{3})_{3}
or Al_{2}(CH_{3})_{6} expresses the molecule of the latter. The
interest of these researches is intimately connected with the
question of the valency of aluminium, if we hold to the opinion
that elements in their various compounds have a constant and
strictly definite valency. In this case the formula AlCl_{3} or
Al(CH_{3})_{3} would show that Al is trivalent, and that
consequently the compounds of aluminium are Al(OH)_{3}, AlO_{3}Al,
and, in general, AlX_{3}. But if the molecule be Al_{2}Cl_{6}, it
is--for the followers of the doctrine of the invariable valency of
the elements--incompatible with the idea of the trivalency of
aluminium, and they assume it to be quadrivalent like carbon,
likening Al_{2}Cl_{6} to ethane C_{2}H_{6} = CH_{3}CH_{3},
although this does not explain why Al does not form AlCl_{4}, or,
in general, AlX_{4}. In this work another supposition is
introduced; according to this, although aluminium, as an element
of group III., gives compounds of the type AlX_{5}, this does not
exclude the possibility of these molecules combining with others,
and consequently with _each other_--that is, forming Al_{2}X_{6};
just as the molecules of univalent elements exist either as H_{2},
Cl_{2}, &c., or as Na, and the molecules of bivalent elements
either as Zn, or as S_{2}, or even S_{6}. In the first place it
must be recognised that the limiting form does not exhaust all
power of combination, it only exhausts the capacity of the element
for combining with X's, but the saturated substance may afterwards
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