The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Since the close of the eighties the metallurgy of aluminium has taken a
new direction, based upon the action of an electric current upon cryolite
at a high temperature,[37] and the solution of oxide of aluminium
(obtained from bauxite or in the form of corundum) in it; under these
conditions metallic aluminium is reduced at the negative pole (cathode)
in a sufficiently pure state, and if the cathode be copper, forms alloys
with it. Such are Hall's and Cowle's (both in the United States) and the
Neuhausen process (where the current is obtained from a dynamo worked by
the Falls of the Rhine at Schaffhausen). As an example, we will describe
(in the words of Prof. D. P. Konovaloff, who became acquainted with this
process at the Chicago Exhibition), Hall's process as applied near
Pittsburg, where it gives about 1,500 kilos of Al a day. An iron box
(about 1 metre long and 1/2 metre wide), provided with a well rammed down
charcoal lining, is charged with a mixture of cryolite and Al_{2}O_{3}
(from bauxite), over which salt is strewn, and a current of 5,000 ampères
at 20 volts is passed through the mixture. The anode is composed of a
carbon cylinder (about 9 cm. in diameter), while the charcoal lining
forms the cathode. When the temperature inside the box is raised to a red
heat by the current, the mixture fuses and the Al_{2}O_{3} begins to
decompose. The Al liberated collects at the bottom of the box, whilst the
oxygen evolved burns the charcoal anode. When the decomposition is at an
end, and the resistance of the mass increases, a fresh quantity of
Al_{2}O_{3} is added, and this is continued until the amount of
impurities accumulated in the furnace and passing into the metal becomes
too great.[37 bis]
[37] Cryolite under the action of the current at about 1,000° gives off
the vapour of Na which reduces the Al, but it recombines with the
liberated fluorine and again passes into the fused mass. It is
important to obtain aluminium at as low a temperature as possible,
but the action proceeds far more easily with the solution (alloy)
of oxide of aluminium in cryolite.
[37 bis] The cost of working this process can be brought as low as 20
cents per lb. or about 2-1/2 fcs. per kilo. In England, Castner,
prior to the introduction of the electric method, obtained Al by
taking a mixture of 1,200 parts of the double salt NaAlCl_{4}, 600
parts of cryolite, and 350 parts of Na, and obtained about 120
parts of Al, so that the cost of this process is about 1-1/2 time
that of the electric method.
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