The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
(_c_) A solution of the salts is partially precipitated by
ammonia; that is, the solution is mixed with a small quantity of
ammonia insufficient for the precipitation of the entire quantity
of the bases (fractional precipitation). Thus, the didymium
hydroxide is first precipitated from a mixture of the salts of
didymium and lanthanum. A partial separation may be effected by
repeating the solution of the precipitate and fractional
precipitation, but a perfectly pure product is scarcely
attainable.
(_d_) The formates having different degrees of solubility
(lanthanum formate 420 parts of water per one of salt, didymium
formate 221, cerium formate 360, yttrium and erbium formates
easily soluble) give a possible means of separating certain of the
gadolinite metals from each other by a method of fractional
solution and precipitation, as Bunsen, Bahr, Clève, and others
have pointed out.
(_e_) Crookes (1893) took advantage of the fractional
precipitation of alcoholic solutions of the chlorides by amylene,
and by this means separated, for example, erbium, terbium, and
others.
(_f_) Lastly, oxide of thorium ThO_{2} (Chapter VIII., Note 59) is
separated by means of its solubility in a solution of sodium
carbonate.
A good method of separating these metals is not known, for they
are so like each other. There are also only a few _methods of
distinguishing_ them from each other, and we can only add the
following four to the above.
^a The faculty of oxidising into a higher oxide. This is very
characteristic for cerium, which gives the oxides Ce_{2}O_{3} and
CeO_{2} or Ce_{2}O_{4}. Didymium also gives one colourless oxide,
Di_{2}O_{3}, which is capable of forming salts (of a lilac
colour), and another, according to Brauner, Di_{2}O_{5} which is
dark brown and does not form salts, so far as is known, and (like
ceric oxide) acts as an oxidising agent, like the higher oxides of
tellurium, manganese, lead, and others. Lanthanum, yttrium, and
many others are not capable of such oxidation. The presence of the
higher oxides may be recognised by ignition in a stream of
hydrogen, by which means the higher oxides are reduced to the
lower, which then remain unaltered.
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