The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The question _of the composition of silica_ was long the subject of
the most contradictory statements in the history of science. In the
last century Pott, Bergmann, and Scheele distinguished silica from
alumina and lime. In the beginning of the present century Smithson
for the first time expressed the opinion that silica was an acid,
and the minerals of rocks salts of this acid. Berzelius determined
the presence of oxygen in silica--namely, that 8 parts of oxygen
were united with 7 of silicon. The composition of silica was first
expressed as SiO (and for the sake of shortness S only was
sometimes written instead). An investigation in the amount of
silica present in crystalline minerals showed that the amount of
oxygen in the bases bears a very varied proportion to the amount of
oxygen in the silica, and that this ratio varies from 2 : 1 to 1 :
3. The ratio 1 : 1 is also met with, but the majority of these
minerals are rare. Other more common minerals contain a larger
proportion of silica, the ratio between the oxygen of the bases and
the oxygen of the silica being equal to 1 : 2, or thereabouts; such
are the augites, labradorites, oligoclase, talc, &c. The higher
ratio 1 : 3 is known for a widely distributed series of natural
silicates--for example, the felspars. Those silicates in which the
amount of oxygen in the bases is equal to that in the silica are
termed _monosilicates_; their general formula will be
(RO)_{2}SiO_{2} or (R_{2}O_{3})_{2}(SiO_{2})_{3}. Those in which
the ratio of the oxygen is equal to 1 : 2 are termed _bisilicates_,
and their general formula will be ROSiO_{2} or
R_{2}O_{3}(SiO_{2})_{3}. Those in which the ratio is 1 : 3 will be
_trisilicates_, and their general formula (RO)_{2}(SiO_{2})_{3} or
(R_{2}O_{3})_{2}(SiO_{2})_{9}.
In these formulæ the now established composition of SiO_{2}--that
is, that in which the atom of Si = 28--is employed. Berzelius, who
made an accurate analysis of the composition of felspar, and
recognised it as a trisilicate formed by the union of potassium
oxide and alumina with silica, in just the same manner as the alums
are formed by sulphuric acid, gave silica the same formula as
sulphuric anhydride--that is, SiO_{3}. In this case the formula of
felspar would be exactly similar to that of the alums--that is,
KAl(SiO_{4})_{2}, like the alums, KAl(SO_{4})_{2}. If the
composition of silica be represented as SiO_{3}, the atom of
silicon must be recognised as equal to 42 (if O = 16; or if O = 8,
as it was before taken to be, Si = 21).
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account