The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Perfectly pure anhydrous silica is not only known in the condition of
rock crystal and quartz having a specific gravity of 2·6, but also in
another special form, having other chemical and physical properties. This
variety of silica has a specific gravity of 2·2, and is formed by fusing
rock crystal or heating silicic acid.[12 bis] Silicic acid, when heated
to a dull red heat, parts entirely with the water it contains, and leaves
an exceedingly fine amorphous mass of silica (easily levigated, but
difficult to moisten); it is characterised by such excessive friability
that, when lightly blown on, a large mass of it rises into the air like a
cloud of dust. A mass of anhydrous silica maybe poured in this way from
one vessel to another like a liquid, and like the latter it takes a
horizontal position in the vessel containing it.[13] Anhydrous silica,
like quartz, does not fuse in the heat of a furnace, but it fuses in the
oxyhydrogen flame to a colourless glassy mass exactly similar to that
formed in the same way from rock crystal. In this condition silica has a
specific gravity of 2·2.[13 bis] Both forms of silica are insoluble in
ordinary acids, and even when they are in the state of powder, alkalis in
solution act very slowly and feebly on them; rock crystal offers much
greater resistance to the action of alkalis than the powder obtained by
heating the hydrate. The latter is quite soluble, although but slowly, in
hot alkaline solutions. This last property appertains in a greater degree
to anhydrous silica having a specific gravity of 2·2 than to that which
has a specific gravity of 2·6. Hydrofluoric acid more easily transforms
the former into silicon fluoride than it does the latter. Both varieties
of silica, when taken in the form of powder, easily combine with bases,
forming, on being fused with an alkali, a vitreous slag, which is a salt
corresponding with silica. Glass is such a salt, formed of alkalis and
alkaline earthy bases; if the glass does not contain any of the
latter--that is, if only alkaline glass be taken--a mass soluble in water
is obtained. In order to obtain such _soluble glass_, potassium or sodium
carbonates, or better a mixture of the two (fusion mixture), is fused
with fine sand. A still better and further saturation of the alkalis with
silica is effected by the action of alkaline solutions on the silicon
hydrate met with in nature; for instance, an alkaline solution is often
made use of to act on the so-called _tripoli_, or collection of siliceous
skeletons of the lowest microscopical infusoria, which is sometimes found
in considerable layers in the form of a sandy mass. Tripoli is used for
polishing, not only on account of the considerable hardness of the
silica, but also because the microscopic bodies of the infusoria have a
pointed shape, which, however, is not angular, so that they do not
scratch metals like sand.[14] The alkaline solutions of silica obtained
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account