The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The increase of atomic weight from silicon 28 to germanium 72 is 44--that
is, about the same difference as there is in the atomic weights of
chlorine and bromine; between germanium and its next analogue, _tin_ (Sn
= 118), the difference is 46--that is, almost as much as the amount by
which the atomic weight of iodine exceeds that of bromine.
Metallic tin is rarely met with in _nature_; it occurs in the veins of
ancient formations, almost exclusively in the form of oxide, SnO_{2},
called _tin-stone_. The best known tin deposits are in Cornwall and in
Malacca. In Russia, tin ores have been found in small quantities on the
shores of Lake Ladoga, in Pitkarand. The crushed ore may easily be
separated from the earthy matter accompanying it by washing on inclined
tables, as the tin-stone has a specific gravity of 6·9, whilst the
impurities are much lighter. _Tin oxide is very easily reduced_ to
metallic tin by heating with charcoal. For this reason tin was known in
ancient times, and the Ph[oe]nicians brought it from England. Metallic
tin is cast into ingots of considerable weight or into thin sticks or
rods. Tin has a white colour, rather duller than that of silver. It fuses
easily at 232°, and crystallises on cooling. Its specific gravity is
7·29. The crystalline structure of ordinary tin is noticed in bending tin
rods, when a peculiar sound is heard, produced by the fracture of the
particles of tin along the surfaces of crystalline structure.
When pure tin is cooled to a low temperature it splits up into separate
crystals, the bond between the particles is lost, the tin assumes a grey
colour, becomes less brilliant--in a word, its properties become changed,
as Fritzsche showed. This depends on the peculiar structure which the tin
then acquires, and is particularly remarkable because it is effected by
cold in a solid.[33 bis] If such tin be fused, or even simply heated, it
becomes like ordinary tin, but is again changed when cooled. When in this
condition tin has a specific gravity of 7·19. Similarly, tin is obtained
by the action of the galvanic current on a solution of tin chloride; it
then appears in crystals of the cubic system, and has a specific gravity
of 7·18--that is, the same as when cooled.[34]
[33 bis] Emilianoff (1890) states that in the cold of the Russian
winter 30 out of 200 tin moulds for candles were spoilt through
becoming quite brittle.
[34] The tin deposited by an electric current from a neutral solution
of SnCl_{2} easily oxidises and becomes coated with SnO (Vignon,
1889).
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