The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The coating of iron by tin, guards it against the direct access of
air, but it only preserves the iron from oxidation so long as it
forms a perfectly continuous coating. If the iron is left bare in
certain places, it will be powerfully oxidised at these spots,
because the tin is electro-negative with respect to the iron, and
thus the oxidation is confined entirely to the iron in the
presence of tin. Hence a coating of tin over iron objects only
partially preserves them from rusting. In this respect a coating
of zinc is more effectual. However, a dense and invariable alloy
is formed over the surface of contact of the iron and tin, which
binds the coating of tin to the remaining mass of the iron. Tin
may be fused with cast iron, and gives a greyish-white alloy,
which is very easily cast, and is used for casting many objects
for which iron by itself would be unsuitable owing to its ready
oxidisability and porosity. The coating of copper objects by tin
is generally done to preserve the copper from the action of acid
liquids, which would attack the copper in the presence of air and
convert it into soluble salts. Tin is not acted on in this manner,
and therefore copper vessels for the preparation of food should be
tinned.
Tin with copper forms _bronze_, an alloy which is most extensively used
in the arts. Bronze has various colours and a variety of physical
properties, according to the relative amount of copper and tin which it
contains. With an excess of copper the alloy has a yellow colour; the
admixture of tin imparts considerable hardness and elasticity to the
copper. An alloy containing 78 parts of copper and about 22 per cent. of
tin is so elastic that it is used for casting bells, which naturally
require a very elastic and hard alloy.[35] For casting statues and
various large or small ornamental articles alloys containing 2 to 5 p.c.
of tin, 10 to 30 p.c. of zinc, and 65 to 85 p.c. of copper are used.[36]
Tin is also often used alloyed with lead, for making various objects--for
instance, drinking vessels.
[35] The ancient Chinese alloys, containing about 20 p.c. of tin
(specific gravity of alloys about 8·9), which have been rapidly
cooled, are distinguished for their resonance and elasticity.
These alloys were formerly manufactured in large quantities in
China for the musical instruments known as _tom-toms_. Owing to
their hardness, alloys of this nature are also employed for
casting guns, bearings, &c., and an alloy containing about 11 p.c.
of tin (corresponding with the ratio Cu_{15}Sn) is known as
gun-metal. The addition of a small quantity of phosphorus, up to 2
p.c., renders bronze still harder and more elastic, and the alloy
so formed is now used under the name of phosphor-bronze.
Public-domain text, read in full here on John Shaqi.
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