The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Tin decomposes the vapour of water when heated with it, liberating the
hydrogen and forming stannic oxide. Sulphuric acid, diluted with a
considerable quantity of water, does not act, or at all events acts very
slightly, on tin, but tin reduces hot strong sulphuric acid, when not
only sulphurous anhydride but also sulphuretted hydrogen is evolved.
Hydrochloric acid acts very easily on tin, with evolution of hydrogen and
formation of stannous chloride, SnCl_{2}, in solution, which, with an
excess of hydrochloric acid and access of air, is converted into stannic
chloride: SnCl_{2} + 2HCl + O = SnCl_{4} + H_{2}O.[36 bis] Nitric acid
diluted with a considerable quantity of water dissolves tin at the
ordinary temperature, whilst the nitric acid itself is reduced, forming,
amongst other products, ammonia and hydroxylamine. Here the tin passes
into solution in the form of stannous nitrate. Stronger nitric acid (also
more dilute, when heated) transforms the tin into its highest grade of
oxidation, SnO_{2}, but the latter then appears as the so-called
metastannic acid, which does not dissolve in nitric acid, and therefore
the tin does not pass into solution. Feeble acids--for instance, carbonic
and organic acids--do not act on tin even in the presence of oxygen,
because tin does not form any powerful bases.
[36 bis] The action of a mixture of hydrochloric acid and tin forms an
excellent means of reducing, wherein both the hydrogen liberated
by the mixture (at the moment of separation) and the stannous
chloride act as powerful reducing and deoxidising agents. Thus,
for instance, by this mixture nitro-compounds are transformed into
amido-compounds--that is, the elements of the group NO_{2} are
reduced to NH_{2}.
It is important to remark as a characteristic of tin that it is reduced
from its solutions by many metals which are more easily oxidised, as, for
instance, by zinc.
_In combination_, _tin_ appears in the two types, SnX_{4} and
SnX_{2},[37] compounds of the intermediate type, Sn_{2}X_{6}, being also
known, but these latter pass with remarkable facility in most cases into
compounds of the higher and lower types, and therefore the form SnX_{3}
cannot be considered as independent.
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