The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
above-mentioned compounds will present themselves in the following
form:--Lead oxide, Pb_{12}O_{12}, its crystalline hydrate,
Pb_{12}O_{8}(OH)_{8}, lead chloride, Pb_{12}Cl_{24}, lead
oxychloride, Pb_{12}Cl_{12}O_{6}, the other oxychloride,
Pb_{12}(OH)_{8}Cl_{6}O_{6}, mendipite (_see_ Note 51),
Pb_{12}Cl_{8}O_{8}, normal lead carbonate, Pb_{12}(CO_{3})_{12},
crystalline basic salt, Pb_{12}(OH)_{6}(CO_{3})_{6}, white lead,
Pb_{12}(CO_{3})_{8}(HO)_{8}, corneous lead,
Pb_{12}Cl_{12}(CO_{3})_{6}, lanarkite,
Pb_{12}(CO_{3})_{6}(SO_{4})_{6}, leadhillite,
Pb_{12}(CO_{3})_{9}(SO_{4})_{3}, &c. The number 12 is only taken
to avoid fractional quantities. Possibly the polymerisation is
much higher than this. The theory of the polymerisation of oxides
introduced by me in the first edition of this work (1869) is now
beginning to be generally accepted.
Amongst the soluble lead salts, that best known and most often applied in
practical chemistry is _lead nitrate_, obtained directly by dissolving
lead or its oxide in nitric acid. The normal salt, Pb(NO_{3})_{2},
crystallises in octahedra, dissolves in water, and has a specific gravity
of 4·5. When a solution of this salt acts on white lead or is boiled with
litharge, the basic salt, having a composition Pb(OH)(NO_{3}), is formed
in crystalline needles, sparingly soluble in cold water but easily
dissolved in hot water, and therefore in many respects resembling lead
chloride. When the nitrate is heated, either lead oxide is obtained or
else the oxide in combination with peroxide.
_Lead chloride_, PbCl_{2}, is precipitated from the soluble salts of
lead when a strong solution is treated with hydrochloric acid or a
metallic chloride. It is soluble in considerable quantities in hot water,
and therefore if the solutions be dilute or hot, the precipitation of
lead chloride does not occur, and if a hot solution be cooled, the salt
separates in brilliant prismatic crystals. It fuses when heated (like
silver chloride), but is insoluble in ammonia. This salt is sometimes met
with in nature, and when heated in air is capable of exchanging half its
chlorine for oxygen, forming the basic salt or lead oxychloride,
PbCl_{2}PbO, which may also be obtained by fusing PbCl_{2} and PbO
together. The reaction of lead chloride with water vapour leads to the
same conclusion, showing the feeble basic character of lead 2PbCl_{2} +
H_{2}O = PbCl_{2},PbO + 2HCl. When ammonia is added to an aqueous
solution of lead chloride a white precipitate is formed, which parts with
water on being heated, and has the composition Pb(OH)Cl,PbO. This
compound is also formed by the action of metallic chlorides on other
soluble basic salts of lead.[51]
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