The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[52] It is remarkable that a peculiar kind of attraction exists between
boiled linseed oil and white lead, as is seen from the following
experiments. White lead is triturated in water. Although it is
heavier than water, it remains in suspension in it for some time
and is thoroughly moistened by it, so that the trituration may be
made perfect; boiled linseed oil is then added, and shaken up with
it. A mixture of the oil and white lead is then found to settle at
the bottom of the vessel. Although the oil is much lighter than
the water it does not float on the top, but is retained by the
white lead and sinks under the water together with it. There is
not, however, any more perfect combination nor even any solution.
If the resultant mass be then treated with ether or any other
liquid capable of dissolving the oil, the latter passes into
solution and leaves the white lead unaltered.
[53] It may be regarded as a salt corresponding with the normal hydrate
of carbonic acid, C(OH)_{4}, in which three-quarters of the
hydrogen is replaced by lead. A salt is also known in which all
the hydrogen of this hydrate of carbonic acid is replaced by
lead--namely, the salt containing CO_{4}Pb_{2}. This salt is
obtained as a white crystalline substance by the action of water
and carbonic acid on lead. The normal salt, PbCO_{3}, occurs in
nature under the name of white lead ore (sp. gr. 6·47), in
crystals, isomorphous with aragonite, and is formed by the double
decomposition of lead nitrate with sodium carbonate, as a heavy
white precipitate. Thus both these salts resemble white lead, but
the first-named salt is exclusively used in practice, owing to its
being very conveniently prepared, and being characterised by its
great covering capacity, or 'body,' due to its fine state of
division.
[53 bis] One of the many methods by which white lead is prepared
consists in mixing massicot with acetic acid or sugar of lead, and
leaving the mixture exposed to air (and re-mixing from time to
time), containing carbonic acid, which is absorbed from the
surface by the basic salt formed. After repeated mixings (with the
addition of water), the entire mass is converted into white lead,
which is thus obtained very finely divided.
[Illustration: FIG. 82.--Manufacture of white lead.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account