The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
hydrate of the composition TiO(OH)_{2}, and when heated it parts
with a still larger proportion of water; at 100° the hydrate
Ti_{2}O_{3}(OH)_{2} is obtained, and at 300° the anhydride itself.
The higher hydrate, Ti(OH)_{4}, is soluble in dilute acid, and the
solution may be diluted with water; but on boiling the sulphuric
acid solution (though not the solution in hydrochloric acid), all
the titanic acid separates in a modified form, which is, however,
not only insoluble in dilute acids, but even in strong sulphuric
acid. This hydrate has the composition Ti_{2}O_{3}(OH)_{2}, but
shows different properties from those of the hydrate of the same
composition described above, and therefore this modified hydrate
is called _metatitanic acid_. It is most important to note the
property of the ordinary gelatinous hydrate (that precipitated
from acid solutions by ammonia) of dissolving in acids, the more
so since silica does not show this property. In this property a
transition apparently appears between the cases of common solution
(based on a capacity for unstable combination) and the case of the
formation of a hydrosol (the solubility of germanium oxide,
GeO_{2}, perhaps presents another such instance). If titanium
chloride be added drop by drop to a dilute solution of alcohol and
hydrogen peroxide, and then ammonia be added to the resultant
solution, a yellow precipitate of _titanium trioxide_,
TiO_{3}H_{2}O, separates out, as Piccini, Weller, and Classen
showed. This substance apparently belongs to the category of true
peroxides.
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