The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
As phosphorus melts at about 40°, it condenses at the bottom of the
receiver in a molten liquid mass, which is cast under water in tubes, and
is sold in the form of sticks. This is common or _yellow phosphorus_. It
is a transparent, yellowish, waxy substance, which is not brittle, almost
insoluble in water, and easily undergoes change in its external
appearance and properties under the action of light, heat, and of various
substances. It crystallises (by sublimation or from its solution in
carbon bisulphide) in the regular system, and[2] (in contradistinction to
the other varieties) is easily soluble in carbon bisulphide, and also
partially in other oily liquids. In this it recalls common sulphur. Its
specific gravity is 1·84. It fuses at 44°, and passes into vapour at
290°; it is easily inflammable, and must therefore be handled with great
caution; careless rubbing is enough to cause phosphorus to ignite. Its
application in the manufacture of matches is based on this.[2 bis] It
emits light in the air owing to its slow[3] oxidation, and is therefore
kept under water (such water is phosphorescent in the dark, like
phosphorus itself). It is also very easily oxidised by various oxidising
agents and takes up the oxygen from many substances.[3 bis] Phosphorus
enters into direct combination with many metals and with sulphur,
chlorine, &c., with development of a considerable amount of heat. It is
very poisonous although not soluble in water.
[2] Vernon (1891) observed that ordinary (yellow) phosphorus is
dimorphous. If it be melted and by careful cooling be brought in a
liquid form to as low a temperature as possible, it gives a variety
which melts at 45°·3 (the ordinary variety fuses at 44°·3), sp. gr.
1·827 (that of the ordinary variety is 1·818) at 13°, crystallises
in rhombic prisms (instead of in forms belonging to the cubical
system). This is similar to the relation between octahedral and
prismatic sulphur (Chapter XX.).
[2 bis] According to Herr Irinyi (an Hungarian student), the first
phosphorus matches were made in Austria at Roemer's works in 1835.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account