The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The researches of Lemoine partially explain the passage of yellow
(ordinary) phosphorus into its other varieties. He heated a closed
glass globe containing either ordinary or red phosphorus, in the
vapour of sulphur (440°), and then determined the amount of the red
and yellow varieties after various periods of time, by treating the
mixture with carbon bisulphide. It appeared that after the lapse of
a certain time a mixture of definite and equal composition is
obtained from both--that is, between the red and yellow varieties a
state of equilibrium sets in like that of dissociation, or that
observed in double decompositions. But at the same time, the
progress of the transformation appeared to be dependent on the
relative quantity of phosphorus taken per volume of the globe
(_i.e._ upon the pressure). Neglecting the latter, we will cite as
an example the amounts of the red phosphorus transformed into the
ordinary, and of the ordinary not converted into red, per 30 grams
of red or yellow taken per litre capacity of the globe, heated to
440°. When red phosphorus was taken, 4·75 grams of yellow
phosphorus were formed after two hours, four grams after eight
hours, three grams after twenty-four hours, and the last limit
remained constant on further heating. When thirty grams of yellow
phosphorus were taken, five grams remained unaltered after two
hours, four grams after eight hours, and after twenty-four hours
and more three grams as before. Troost and Hautefeuille showed that
liquid phosphorus in general changes more easily into the red than
does phosphorus vapour, which, however, is able, although slowly,
to deposit red phosphorus.
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