The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[28] We are already acquainted with some of the chloranhydrides of the
inorganic acids--for instance, BCl_{3}, and SiCl_{4}--and here we
shall describe those which correspond with sulphuric acid in the
following chapter. It may be mentioned here that when hydrochloric
acts on nitric acid (aqua regia, Vol. I. p. 467) there is formed,
besides chlorine, the oxychlorides NOCl and NO_{2}Cl, which may be
regarded as chloranhydrides of nitric and nitrous acids (nitrogen
chloride, Vol. I. p. 476). The former boils at -5°, the latter at
+5°, the specific gravity of the first at -12° = 1·416, and at
-18° = 1·433 (Geuther), and of the second = 1·3; the first is
obtained from nitric oxide and chlorine, the second from nitric
peroxide and chlorine, and also by the action of phosphoric
chloride on nitric acid. If the gases evolved by aqua regia be
passed into cold and strong sulphuric acid, they form crystals of
the composition NHSO_{3} (like chamber crystals), which melt at
86°, and with sodium chloride form acid sodium sulphate and the
oxychloride NOCl. This chloranhydride of nitric acid is termed
_nitrosyl chloride_.
_Cyanogen chloride_, CNCl, is the gaseous chloranhydride of cyanic
acid; it is formed by the action of chlorine on aqueous mercury
cyanide, Hg(CN)_{2} + 2Cl_{2} = HgCl_{2} + 2CNCl. When chlorine
acts on cyanic acid, it forms not only this cyanogen chloride, but
also polymerides of it--a liquid, boiling at 18°, and a solid,
boiling at 190°. The latter corresponds with cyanuric acid, and
consequently contains C_{3}N_{3}Cl_{3}. Details concerning these
substances must be looked for in works on organic chemistry.
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