The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
the normal salt, K_{3}AsO_{4}, is formed by fusing the other
potassium arsenates with potassium carbonate; it is soluble in
water and crystallises in needles which do not contain water.
Di-potassium arsenate, K_{2}HAsO_{4}, is formed in solution by
mixing potassium carbonate and arsenic acid until carbonic
anhydride ceases to be evolved; it does not crystallise, and has
an alkaline reaction; hence it corresponds perfectly with the
sodium phosphate. As was mentioned above, arsenic acid itself acts
as an oxidising agent; for example, it is used in the manufacture
of aniline dyes for oxidising the aniline, and it is prepared in
large quantities for this purpose. When sulphuretted hydrogen is
passed through its solution, sulphuric acid and arsenious
anhydride are obtained in solution. Arsenic acid is very easily
soluble in water, and its solution has an exceedingly acid
reaction, and when boiled with hydrochloric acid evolves chlorine,
like selenic, chromic, manganic, and certain other higher metallic
acids.
_Arsenic anhydride_, As_{2}O_{5}, is produced when arsenic acid is
heated to redness. It must be carefully heated, as at a bright red
heat it decomposes into oxygen and arsenious anhydride. Arsenic
anhydride is an amorphous substance almost entirely insoluble in
water, but it attracts moisture from the air, deliquesces, and
passes into the acid. Hot water produces this transformation with
great ease.
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