The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[40] Printers' type consists of an alloy known as 'type-metal,'
containing usually about 15 parts of antimony to 85 parts of lead;
sometimes (for example, for stereotypes) from 10 to 15 per cent.
Bi or 8 per cent. Sn and even Cu is added. The hardness of the
alloy, which is essential for printing, evidently depends upon the
presence of antimony, but an excess must be avoided, since this
renders the alloy brittle, and the type after a time loses its
sharpness.
[40 bis] Antimony is prepared in a state of greater purity by heating
with charcoal the oxide obtained by the action of nitric acid on
the impure commercial metallic antimony. This is based on the fact
that by the action of the acid, antimony forms the oxide
Sb_{2}O_{3}, which is but slightly soluble in water. The arsenic,
which is nearly always present, forms soluble arsenious and
arsenic acids, and remains in solution. The purest antimony is
easily obtained from tartar emetic, by heating it with a small
quantity of nitre. Metallic antimony also occurs, although rarely,
native; and as it is very easily obtained, it was known to the
alchemists of the fifteenth century. Very pure metallic antimony
may be deposited by the electric current from a solution of
antimonious sulphide in sodium sulphide after the addition of
sodium chloride to the solution.
Metallic antimony has a white colour and a brilliant lustre; it remains
untarnished in the air, for the metal does not oxidise at the ordinary
temperature. It crystallises in rhombohedra, and always shows a
distinctly crystalline structure which gives it quite a different aspect
from the majority of the metals yet known. It is most like tellurium in
this respect. Antimony is brittle, so that it is very easily powdered;
its specific gravity is 6·7, it melts at about 432°, but only volatilises
at a bright red heat. When heated in the air--for instance, before the
blow-pipe--it burns and gives white odourless fumes, consisting of the
oxide. This oxide is termed antimonious oxide, although it might as well
be termed antimonious anhydride. It is given the first name because in
the majority of cases its compounds with acids are used, but it forms
compounds with the alkalis just as easily.
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