The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
law of nature, as I did from the very beginning (1869).
[14] When in 1871 I wrote a paper on the application of the periodic
law to the determination of the properties of hitherto
undiscovered elements, I did not think I should live to see the
verification of this consequence of the law, but such was to be
the case. Three elements were described--ekaboron, ekaaluminium,
and ekasilicon--and now, after the lapse of twenty years, I have
had the great pleasure of seeing them discovered and named
Gallium, Scandium, and Germanium, after those three countries
where the rare minerals containing them are found, and where they
were discovered. For my part I regard L. de Boisbaudran, Nilson,
and Winkler, who discovered these elements, as the true
corroborators of the periodic law. Without them it would not have
been accepted to the extent it now is.
[15] Taking indium, which occurs together with zinc, as our example, we
will show the principle of the method employed. The equivalent of
indium to hydrogen in its oxide is 37·7--that is, if we suppose
its composition to be like that of water; then In = 37·7, and the
oxide of indium is In_{2}O. The atomic weight of indium was taken
as double the equivalent--that is, indium was considered to be a
bivalent element--and In = 2 × 37·7 = 75·4. If indium only formed
an oxide, RO, it should be placed in group II. But in this case it
appears that there would be no place for indium in the system of
the elements, because the positions II., 5 = Zn = 65 and II., 6 =
Sr = 87 were already occupied by known elements, and according to
the periodic law an element with an atomic weight 75 could not be
bivalent. As neither the vapour density nor the specific heat, nor
even the isomorphism (the salts of indium crystallise with great
difficulty) of the compounds of indium were known, there was no
reason for considering it to be a bivalent metal, and therefore it
might be regarded as trivalent, quadrivalent, &c. If it be
trivalent, then In = 3 × 37·7 = 113, and the composition of the
oxide is In_{2}O_{3}, and of its salts InX_{3}. In this case it at
once falls into its place in the system, namely, in group III. and
7th series, between Cd = 112 and Sn = 118, as an analogue of
aluminium or dvialuminium (dvi = 2 in Sanskrit). All the
properties observed in indium correspond with this position; for
example, the density, cadmium = 8·6, indium = 7·4, tin = 7·2; the
basic properties of the oxides CdO, In_{2}O_{3}, SnO_{2},
successively vary, so that the properties of In_{2}O_{3} are
intermediate between those of CdO and SnO_{2} or Cd_{2}O_{2} and
Sn_{2}O_{4}. That indium belongs to group III. has been confirmed
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