The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[13] The laws of nature admit of no exceptions, and in this they
clearly differ from such rules and maxims as are found in grammar,
and other inventions, methods, and relations of man's creation.
The confirmation of a law is only possible by deducing
consequences from it, such as could not possibly be foreseen
without it, and by verifying those consequences by experiment and
further proofs. Therefore, when I conceived the periodic law, I
(1869-1871, Note 9) deduced such logical consequences from it as
could serve to show whether it were true or not. Among them was
the prediction of the properties of undiscovered elements and the
correction of the atomic weights of many, and at that time little
known, elements. Thus uranium was considered as trivalent, U =
120; but as such it did not correspond with the periodic law. I
therefore proposed to double its atomic weight--U = 240, and the
researches of Roscoe, Zimmermann, and others justified this
alteration (Chapter XXI.). It was the same with cerium (Chapter
XVIII.) whose atomic weight it was necessary to change according
to the periodic law. I therefore determined its specific heat, and
the result I obtained was verified by the new determinations of
Hillebrand. I then corrected certain formulæ of the cerium
compounds, and the researches of Rammelsberg, Brauner, Clève, and
others verified the proposed alteration. It was necessary to do
one or the other--either to consider the periodic law as
completely true, and as forming a new instrument in chemical
research, or to refute it. Acknowledging the method of experiment
to be the only true one, I myself verified what I could, and gave
every one the possibility of proving or confirming the law, and
did not think, like L. Meyer (Liebig's _Annalen, Supt. Band 7_,
1870, 364), when writing about the periodic law that 'it would be
rash to change the accepted atomic weights on the basis of so
uncertain a starting-point.' ('Es würde voreilig sein, auf so
unsichere Anhaltspunkte hin eine Aenderung der bisher angenommenen
Atomgewichte vorzunehmen.') In my opinion, the basis offered by
the periodic law had to be verified or refuted, and experiment in
every case verified it. The starting-point then became general. No
law of nature can be established without such a method of testing
it. Neither De Chancourtois, to whom the French ascribe the
discovery of the periodic law, nor Newlands, who is put forward by
the English, nor L. Meyer, who is now cited by many as its
founder, ventured to foretell the _properties_ of undiscovered
elements, or to alter the 'accepted atomic weights,' or, in
general, to regard the periodic law as a new, strictly established
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