The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
and palladium, and of osmium, iridium, and platinum, are very close to
each other, and their properties are also very much alike--the
differences are not very perceptible. And if the properties of atoms are
a function of their weight, many ideas which have more or less rooted
themselves in chemistry must suffer change and be developed and worked
out in the sense of this deduction. Although at first sight it appears
that the chemical elements are perfectly independent and individual,
instead of this idea of the nature of the elements, the notion of the
dependence of their properties upon _their mass_ must now be established;
that is to say, the subjection of the individuality of the elements to a
common higher principle which evinces itself in gravity and in all
physico-chemical phenomena. Many chemical deductions then acquire a new
sense and significance, and a regularity is observed where it would
otherwise escape attention. This is more particularly apparent in the
physical properties, to the consideration of which we shall afterwards
turn, and we will now point out that Gustavson first (Chapter X., Note
28) and subsequently Potilitzin (Chapter XI., Note 66) demonstrated the
direct dependence of the reactive power on the atomic weight and that
fundamental property which is expressed in the forms of their compounds,
whilst in a number of other cases the purely chemical relations of
elements proved to be in connection with their periodic properties. As a
case in point, it may be mentioned that Carnelley remarked a dependence
of the decomposability of the hydrates on the position of the elements in
the periodic system; whilst L. Meyer, Willgerodt, and others established
a connection between the atomic weight or the position of the elements in
the periodic system and their property of serving as media in the
transference of the halogens to the hydrocarbons.[16] Bailey pointed out
a periodicity in the stability (under the action of heat) of the oxides,
namely: (_a_) in the even series (for instance, CrO_{3}, MoO_{3}, WO_{3},
and UO_{3}) the higher oxides of a given group decompose with greater
ease the smaller the atomic weight, while in the uneven series (for
example, CO_{2}, GeO_{2}, SnO_{2}, and PbO_{2}) the contrary is the case;
and (_b_) the stability of the higher saline oxides in the even series
(as in the fourth series from K_{2}O to Mn_{2}O_{7}) decreases in passing
from the lower to the higher groups, while in the uneven series it
increases from the Ist to the IVth group, and then falls from the IVth to
the VIIth; for instance, in the series Ag_{2}O, CdO, In_{2}O_{3},
SnO_{2}, and then SnO_{2}, Sb_{2}O_{5}, TeO_{3}, I_{2}O_{7}. K. Winkler
looked for and actually found (1890) a dependence between the
reducibility of the metals by magnesium and their position in the
periodic system of the elements. The greater the attention paid to this
field the more often is a distinct connection found between the variation
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