The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
7. The periodic variability of the properties of the elements in
dependence on their masses presents a distinction from other kinds of
periodic dependence (as, for example, the sines of angles vary
periodically and successively with the growth of the angles, or the
temperature of the atmosphere with the course of time), in that the
weights of the atoms do not increase gradually, but by leaps; that is,
according to Dalton's law of multiple proportions, there not only are
not, but there cannot be, any transitive or intermediate elements between
two neighbouring ones (for example, between K = 39 and Ca = 40, or Al =
27 and Si = 28, or C = 12 and N = 14, &c.) As in a molecule of a hydrogen
compound there may be either one, as in HF, or two, as in H_{2}O, or
three, as in NH_{3}, &c., atoms of hydrogen; but as there cannot be
molecules containing 2-1/2 atoms of hydrogen to one atom of another
element, so there cannot be any element intermediate between N and O,
with an atomic weight greater than 14 or less than 16, or between K and
Ca. Hence the periodic dependence of the elements cannot be expressed by
any algebraical continuous function in the same way that it is possible,
for instance, to express the variation of the temperature during the
course of a day or year.
8. The essence of the notions giving rise to the periodic law consists
in a general physico-mechanical principle which recognises the
correlation, transmutability, and equivalence of the forces of nature.
Gravitation, attraction at small distances, and many other phenomena are
in direct dependence on the mass of matter. It might therefore have been
expected that chemical forces would also depend on mass. A dependence is
in fact shown, the properties of elements and compounds being determined
by the masses of the atoms of which they are formed. The weight of a
molecule, or its mass, determines, as we have seen, (Chapter VII. and
elsewhere) many of its properties independently of its composition. Thus
carbonic oxide, CO, and nitrogen, N_{2}, are two gases having the same
molecular weight, and many of their properties (density, liquefaction,
specific heat, &c.) are similar or nearly similar. The differences
dependent on the nature of a substance play another part, and form
magnitudes of another order. But the properties of atoms are mainly
determined by their mass or weight, and are in dependence upon it. Only
in this case there is a peculiarity in the dependence of the properties
on the mass, for this _dependence is determined by a periodic law_. As
the mass increases the properties vary, at first successively and
regularly, and then return to their original magnitude and recommence a
fresh period of variation like the first. Nevertheless here as in other
cases a small variation of the mass of the atom generally leads to a
small variation of properties, and determines differences of a second
order. The atomic weights of cobalt and nickel, of rhodium, ruthenium,
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