The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In this respect it may not be superfluous to remark (1) that
Thomsen, whose results I have employed above, observed a
correlation in the calorific equivalents of analogous elements,
although he did not remark their periodic variation; (2) that the
uniformity of many thermochemical deductions must gain
considerably by the application of the periodic law, which
evidently repeats itself in calorimetric data; and if these data
frequently lead to true forecasts, this is due to the periodicity
of the thermal as well as of many other properties, as Laurie
remarked; and (3) that the heat of formation of the oxides is also
subject to a periodic dependence which differs from that of the
heat of formation of the chlorides, in that the greatest quantity
corresponds with the bivalent metals of the alkaline earths
(magnesium, calcium, strontium, barium), and not with the
univalent metals of the alkalis, as is the case with chlorine,
bromine, and iodine. This circumstance is probably connected with
the fact that chlorine, bromine, and iodine are univalent
elements, and oxygen bivalent (compare, for instance, Chapter XI.,
Note 13, Chapter XXII., Note 40, Chapter XXIV., Note 28^{bis},
&c.)
Keyser (1892), in investigating the spectra of the alkali metals
and metals of the alkaline earths, came to the conclusion that in
this respect also there is a regularity of a periodic character in
dependence upon the atomic weights. Probably a closer and
systematic study of many of the properties of the elements and of
complex and simple bodies formed by them will more and more
frequently lead to similar conclusions, and to extending the range
of application of the periodic law.
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