The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
There is no doubt that many other physical properties will, when
further studied, also prove to be in periodic dependence on the atomic
weights,[19 bis] but at present only a few are known with any
completeness, and we will only refer to the one which is the most easily
and frequently determined--namely, the _specific gravity_ in a solid and
liquid state, the more especially as its connection with the chemical
properties and relations of substances is shown at every step. Thus, for
instance, of all the metals those of the alkalis, and of all the
non-metals the halogens, are the most energetic in their reactions, and
they have the lowest specific gravity among the adjacent elements, as is
seen in Table III., column 17. Such are sodium, potassium, rubidium,
cæsium among the metals, and chlorine, bromine, and iodine among the
non-metals; and as such less energetic metals as iridium, platinum, and
gold (and even charcoal or the diamond) have the highest specific gravity
among the elements near to them in atomic weight; therefore the degree of
the condensation of matter evidently influences the course of the
transformations proper to a substance, and furthermore this dependence on
the atomic weight, although very complex, is of a clearly periodic
character. In order to account for this to some extent, it may be
imagined that the lightest elements are porous, and, like a sponge, are
easily penetrated by other substances, whilst the heavier elements are
more compressed, and give way with difficulty to the insertion of other
elements. These relations are best understood when, instead of the
specific gravities referring to a unit of volume,[20] the _atomic volumes
of the elements_--that is, the quotient _A_/_d_ of the atomic weight _A_
by the specific gravity _d_--are taken for comparison. As, according to
the entire sense of the atomic theory, the actual matter of a substance
does not fill up its whole cubical contents, but is surrounded by a
medium (ethereal, as is generally imagined), like the stars and planets
which travel in the space of the heavens and fill it, with greater or
less intervals, so the quotient _A_/_d_ only expresses the _mean_ volume
corresponding to the sphere of the atoms, and therefore [3root]_A_/_d_
_is the mean distance between the centres of the atoms_. For compounds
whose molecules weigh _M_, the mean magnitude of the atomic volume is
obtained by dividing the mean molecular volume _M_/_d_ by the number of
atoms _n_ in the molecule.[21] The above relations may easily be
expressed from this point of view by comparing the atomic volumes. Those
comparatively light elements which easily and frequently enter into
reaction have the greatest atomic volumes: sodium 23, potassium 45,
rubidium 57, cæsium 71, and the halogens about 27; whilst with those
elements which enter into reaction with difficulty, the mean atomic
volume is small; for carbon in the form of a diamond it is less than 4,
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