The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[5] This mineral has been given the name of 'mock-ore,' on account of
its having the appearance (considerable density, 4·06, &c.) of
ordinary metallic ores; it deceived the first miners, because it
did not, like other ores, give metal when simply roasted in air and
fused with charcoal. The white zinc oxide, formed by burning the
vapours of zinc, was also called 'nihil album,' or 'white nothing,'
on account of its lightness.
[Illustration: FIG. 80.--Distillation of zinc in a crucible placed in a
furnace. _o c_, tube along which the vapour passes and condenses.]
Metallic zinc (spelter) is most frequently obtained from the ores
containing the carbonate[6]--that is, from calamine, which is sometimes
found in thick veins: for instance, in Poland, Galicia, in some places on
the banks of the Rhine, and in considerable masses in Belgium and
England. In Russia beds of zinc ore are met with in Poland and the
Caucasus, but the output is small. In Sweden, as early as the fifteenth
century, calamine was worked up into an alloy of zinc and copper (brass),
and Paracelsus produced zinc from calamine; but the technical production
of the metal itself, long ago practised in China, only commenced in
Europe in 1807--in Belgium, when the Abbé Donnet discovered that zinc was
volatile. From that time the production increased until it is now about
150 million kilograms in Germany alone.
[6] It may be here mentioned that by the word _ore_ is meant a hard,
heavy substance dug out of the earth, which is used in
metallurgical works for obtaining the usual heavy metals long known
and used. The natural compounds of sodium, or magnesium, are not
called ores, because magnesium and sodium have not been long
obtainable in quantity. The heavy metals, those which are easily
reduced and do not easily oxidise, are exclusively those which are
directly applied in manufactures. Ores either contain the metals
themselves (for instance, ores of silver or bismuth), and the
metals are then said to be in a native state, or else their sulphur
compounds (blende, mock-ore, pyrites--as, for example, galena, PbS;
zinc blende, ZnS; copper pyrites, CuFeS) or oxides (as the ores of
iron), or salts (calamine, for instance). Zinc is incomparably
rarer than magnesium, and is only well known because it is
transformed from its ores into a metal which finds direct use in
many branches of industry.
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