The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
calomel passes (at about 465°) through a porous clay cell,
containing calomel. This proves that the vapour of calomel
contains a mixture of the vapours of Hg and HgCl_{2}, as would
follow from the second hypothesis. Moreover, on introducing a
heated piece of KHO into the vapour of calomel, Meyer observed the
formation, not of suboxide (black), but of oxide of mercury
(yellow). Therefore the molecular formula of calomel must be taken
as Hg_{2}Cl_{2} (and not HgCl).
The lowest oxygen compound of mercury--that is, _mercurous oxide_,
Hg_{2}O--does not seem to exist, for the substance precipitated in the
form of a black mass by the action of alkalis on a solution of mercurous
salts gradually separates on keeping into the yellow mercuric oxide and
metallic mercury, as does also a simple mechanical mixture of oxide, HgO,
with mercury (Guibourt, Barfoed). The other compound of mercury with
oxygen is already known to us as _mercuric oxide_, HgO, obtained in the
form of a red crystalline substance by the oxidation of mercury in the
air, and precipitated as a yellow powder by the action of sodium
hydroxide on solutions of salts of the type HgX_{2}. In this case it is
amorphous and more amenable to the action of various reagents (Chap. XI.,
Note 32) than when it is in the crystalline state. Indeed, on
trituration, the red oxide is changed into a powder of a yellow colour.
It is very sparingly soluble in water, and forms an alkaline solution
which precipitates magnesia from the solution of its salts.
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