The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
If we imagine that the NO_{2} is
replaced by hydrogen, we shall have a substance of the composition
C_{2}H_{3}N. This is acetonitrile--that is, acetic acid + NH_{3} -
2H_{2}O, or ethenyl nitrile, as shown in Chapter VI. The formation
of an acetic compound by the action of nitric acid on alcohol is
easily understood, because acetic acid is produced by the
oxidation of alcohol, and the production of the elements of
ammonia, indispensable for the formation of a nitrile, is
accounted for by the fact that nitric acid under the action of
reducing substances in many cases forms ammonia. Moreover a
certain analogy has been found between fulminating acid and
hydroxylamine, but details upon this subject must be looked for in
works on organic chemistry. The explosiveness of fulminating
mercury, the rapidity of its decomposition (gunpowder, and even
guncotton, burn more slowly and explode less violently), and the
force of its explosion, are such that a small quantity (loosely
covered) will shatter massive objects.
The investigations of Abel on the communication of explosion from
one substance to another are remarkable. If guncotton be ignited
in an open space, it burns quietly; but if fulminating mercury be
exploded by the side of it, the decomposition of the guncotton is
effected instantaneously, and it then shatters the objects upon
which it lies, so rapid is the decomposition. Abel explains this
by supposing that the explosion of the fulminating salt brings the
molecules of guncotton into a uniform or as it were harmonious
state of vibration, which causes the rapid decomposition of the
whole mass. This rapid decomposition of explosive substances
defines the distinction between explosion and combustion. Besides
this, Berthelot showed that from that form of powerful molecular
concussion which takes place during the explosion of fulminating
mercury, the state of strain and stability of equilibrium of
substances which are endothermal, or capable of decomposing with
the disengagement of heat--for instance, cyanogen, nitro
compounds, nitrous oxide, &c.--is generally destroyed. Thorpe
showed that carbon bisulphide, CS_{2}, also an endothermal
substance, decomposes into sulphur and charcoal, when fulminating
mercury is exploded in contact with it.
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