The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
for further portions of water to gain access to the interior of the
powdery mass. On the other hand, if it is “drowned” by excess, the
temperature is lowered, the process goes on slowly, and the mass does
not readily fall into powder, and so fails to be utilised in the liming
process. Of all methods of slaking lime, the ordinary one of tipping it
direct into the lime-pits is perhaps the most irrational, leading to the
formation of unslaked lumps which may burn the hides, and which,
together with stones and dirt, rapidly choke the pits with useless
matter. The best process is that adopted by builders and in many
Continental yards, in which a large quantity of lime is slaked in a
shallow tank by throwing on it sufficient water to thoroughly wet it,
and after allowing it to heat and fall for 24 hours, adding enough water
to convert it into a stiff paste. In this form it may be kept for months
without material deterioration. When required for use, a suitable
quantity of the paste is dug out, and well stirred with water in a tub
or tank before running into the pit when the stones and sand remain in
the tank. In this way all nuisance from dust is also avoided. If lime is
stored unslaked, it gradually absorbs moisture from the air, falling,
and soon becoming dusty and difficult to slake completely, while the
traces of carbon dioxide in the air gradually convert it into useless
carbonate.
[69] Bull. de la Soc. d’Encouragement, 1895, x. pp. 52-62; Journ. Soc.
Chem. Ind., 1895, p. 575.
The solubility of lime in water is very limited, and the figures
determined by different chemists do not agree very satisfactorily. The
following table gives the result of determinations made by Mr. A.
Guthrie in the Author’s laboratory, and is probably one of the most
accurate[70]:--
100 c.c. of saturated lime water at 5° C. contain 0·1350 grm. of CaO.
„ „ 10° „ 0·1342 „
„ „ 15° „ 0·1320 „
„ „ 20° „ 0·1293 „
„ „ 25° „ 0·1254 „
„ „ 30° „ 0·1219 „
„ „ 35° „ 0·1161 „
„ „ 40° „ 0·1119 „
„ „ 50° „ 0·0981 „
„ „ 60° „ 0·0879 „
„ „ 70° „ 0·0781 „
„ „ 80° „ 0·0740 „
„ „ 90° „ 0·0696 „
„ „ 100° „ 0·0597 „
[70] Journ. Soc. Chem. Ind., 1901, p. 224.
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