The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Von Schroeder has found that a strength of 6 grams of calcium oxide
(CaO) per liter was sufficient, but, in practice, much more is generally
added. It is also noteworthy that a perfectly fresh milk of lime must be
made much stronger than one which has been used. This is partially due
to the fact that some bacterial action takes place in an old lime and
that ammonia is formed which assists unhairing, in addition to the
effect of the lime itself, and partially because the lime in old liquors
remains in suspension for a much longer time, and is thus more evenly
distributed.
A method of liming, sometimes known as the “Buffalo method,” has been
largely adopted for sole-leather in America, and is now used in many
Continental yards. It consists in a very short liming and the subsequent
use of warm water. The limes are also often sharpened by the addition of
a little sodium sulphide or of some other sulphide. Thus, in one large
yard in the States, the hides for sole-leather (salted “packers”) are
limed for 10 hours only with 2 lb. lime and 2¹⁄₂ oz. of sulphide of
sodium per side, and after lying overnight in water of a temperature of
35-45° C., are easily unhaired. A Continental firm lime two days in weak
fresh limes with a little tank-waste, and then treat with water at 32°
C. for 6-8 hours, when the hides are unhaired and returned to the warm
water for two hours before scudding. All sorts of combinations between
liming and hot water treatment can be employed. The longer and stronger
the liming, the lower temperature or shorter time in the water will
suffice. The method is much to be recommended for firm sole-leather, but
it does not saponify grease or swell the fibres thoroughly, and usually
vitriol is used for the latter purpose in a later stage. The hide goes
into the liquors practically free of lime, and the loss of
hide-substance is much less than in the ordinary method of liming.
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