The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
_Drenching_ is occasionally used (e.g. on calf-kid) as a substitute for
bating or puering, but more frequently follows the latter, and serves to
cleanse and slightly plump the skins before tanning, and complete the
removal of lime. The drench-liquor is an infusion of bran made with hot
water, and allowed to ferment under the influence of special bacteria,
which are always present in vats used for the purpose, and which
develop lactic and acetic acids.
It will be noted that all these methods are fermentative, and their
effect is not simply the chemical one of removing the lime, but the
bacterial action leads also to solution of the cementing substance of
the hide-fibres, and produces a marked softening effect on the leather,
together with considerable loss of hide-substance. In the manufacture of
the softer leathers this effect is generally desired, and no process
would be satisfactory which did not produce it; but in other cases, such
as harness- and strap-butts, firmer and heavier weighing leathers would
be preferred, if it were known how to make them. The putrefactive
processes would be gladly relinquished, if satisfactory substitutes
could be found, not only on account of their offensive character, but
because of their uncertainty and danger to the goods; and even if lime
only were removed, the necessary softness could often be obtained by
appropriate liming and tanning.
It will be best, therefore, to deal first with the purely chemical
methods which aim only at removal of lime, before considering those
involving bacterial action. Unfortunately, the chemical problem is not
so simple as it might at first sight appear. The alkaline lime clings
obstinately to the hide-fibre, and can only be removed very slowly, if
at all, by mere washing. On the other hand, the use of any excess of
strong acid is absolutely precluded, because of its powerful swelling
effect on the pelt, in the tanning of which it would prove even more
injurious than the lime, making dark-coloured and brittle, or tender,
leather. This effect is not to be avoided by the use of even very dilute
solutions of strong acids, since the affinity of hide-fibre for them is
so strong that it will abstract practically all the acid from even a
decinormal solution, leaving it quite neutral. What is required is an
acid of extremely weak affinities, forming soluble lime salts, and
obtainable at a low cost; or, on the other hand, a salt of some weak
base which could be displaced by lime, and which would not act
injuriously on the pelt. With certain precautions, and in special cases,
however, the stronger acids may be used successfully.
Public-domain text, read in full here on John Shaqi.
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