The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
A bating liquor which was proposed by the writer, and which has been
used with some success on harness-leather, is made up with a ¹⁄₄ lb. of
good white ammonium chloride (sal ammoniac) and a ¹⁄₄ lb. of Boakes’
“metabisulphite of soda” per hide, and for successive packs sufficient
sulphuric acid to neutralise the ammonia formed, together with a small
quantity of metabisulphite and ammonium chloride to restore that carried
out by the hides is added. It is probable that this would also answer
well for deliming sole-leather as it entirely removes lime without
pulling down the hides much, and they would remain still plumper if
ammonium sulphate were substituted for ammonium chloride, while the
sulphuric acid might be safely increased till the liquor was but
slightly alkaline when the bating was finished. About 2-4 oz. of good
white oil of vitriol is required per hide, but the exact quantity will
depend on the mode of liming, and the amount of washing the hides
receive before going into the bate, and can therefore be only
ascertained by experience. As no free sulphuric acid can exist in the
liquor so long as the quantity of metabisulphite is maintained, there is
no practical danger of spoiling the leather if the acid be in slight
excess. The quantities given may in most cases be advantageously
diminished, since it is not always advisable in practice to remove the
whole of the lime, which in small quantity renders tannage and
penetration of the liquor much more rapid, either by acting as a mordant
to the tannin, or by temporarily neutralising it and diminishing its
astringent action on the hide-fibre.
Turning to dressing leather, we find that the use of cold water alone
has been practically abandoned in this country, though the finest French
calf is produced by repeated soakings in cold water with alternate
workings over the beam, sometimes extending to nine or more. In this
case, from the lengthened exposure to waters which are only gradually
renewed it is probable that putrefactive action takes place, and that a
sort of bating is effected by the decomposing products of the hide
itself; in fact, in many French yards, bran-drenches have been
introduced to supplement the action of the water alone. Waters differ
greatly in their power of removing lime from skin. Slightly acid and
peaty waters, and those in general which contain much organic matter,
are much more powerful in reducing than those which are purer (cp. p.
107).
Warm water has much more effect in removing lime than cold, since the
heat lessens the risk of dissolved carbonic acid, and seems to have a
direct depleting effect on the pelt. A good tumbling in warm soft water
will remove a great deal of lime, and is an excellent preparation for
bating, but heat must be used cautiously, and should never exceed
30°-35° C.; some skins, such as seals, being very readily tendered by
its action, while others, especially sheep-skins, will stand a
comparatively high temperature.
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