The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Starting from the presumption that bating and puering are, in the main,
bacterial processes, more or less successful attempts had been made
previous to those of Wood, Popp and Becker, to substitute other
fermenting substances for dung; and probably these efforts failed in
many cases, not so much because they were wrong in principle, as from
want of knowledge of the necessary details, such as the use of proper
ferments, and the provision of suitable culture-media. Guano, prepared
horse-flesh, urine, yeast, and fermenting vegetables have all been
tried. A solution of glucose or treacle of about 10 per cent., to which
3 per cent. of pasty dog-puer is added about a week before use, was
tried many years since in a morocco-factory, at the suggestion of the
writer, as at least a partial substitute for puer, and is still in use
there. The mixture keeps for some time in an active state, and is added
to the puer liquors in the same way and in approximately the same
proportions as the dung paste. Similar in principle is the solid bate
supplied by an American firm, in which glucose is mixed with a small
amount of nitrogenous matter and phosphates, together with a lactic
ferment, and which only requires dissolving in warm water some little
time before use. Its results are good for some purposes, but rather
resemble those of a drench than a bate. In a similar way, puer may be
added to bran-drench liquors, and induces in them a fermentation which
brings the skins down much lower than the ordinary drench. It is
probable that a weak glucose solution, with traces of mineral
constituents similar to Cohn’s solution (see L.I.L.B., p. 269) and “set”
with sour milk, or fermenting drench-liquor, might in some cases be used
with advantage for drenching, with a saving of cost. A writer in ‘Hide
and Leather’ describes a bate in which two parts by weight of glucose
are dissolved in about 25 parts of water, and fermented, for about three
days, till a foam gathers on the top, with about one part of old bran
drench-liquor, or 0·1 part of pressed yeast, and then made up with water
to 1000 parts. The goods are bated 24-36 hours at a temperature of about
35° C, and the bate is strengthened for a second pack with about
one-fifth of the original glucose, a new bate being made at the end of a
week, and set with one part per thousand of the old one. A short bating
of say 10 hours produced very nice harness-leather, but the general
tendency was to make the goods looser and more spongy than a dung-bate.
It is obviously not a matter of indifference whether old drench, or
yeast, is used to start the fermentation, since in the latter case only
alcohol could be produced directly by the ferment introduced, though
this might be fermented later, by other accidental organisms, into
acetic acid. These mixed bates, containing glucose, are however probably
wrong in principle, since the true puering and bating bacteria will not
thrive in presence of acids, and require nitrogenous nutriment.
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