The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
Numerous patents have been taken for processes of chrome tannage. The
first practical method was described by Professor Knapp in 1858 (see p.
210), though he did not recognise its value. Some of the patents have a
historical interest, though of no importance. Among these may be
mentioned that of Cavallin, a Swedish apothecary, whose object was
dyeing rather than tanning, but who treated raw hide with a solution of
bichromate, which was afterwards reduced on the fibre by one of ferrous
sulphate. The leather produced is dark reddish brown, and tender from
the amount of basic ferric salt formed at the same time. Mr. J. W. Swan,
well known in connection with photographic processes, and electric
lighting, also patented a process of chrome tannage (as an addendum to a
patent on carbon printing), in which the chromic acid first fixed in the
pelt was reduced by “oxalic, or other suitable acid.” Although it is
possible to produce leather within the lines of the patent, the
strongly acid reaction of the reducing agent renders it unsuitable for
practical use. The first chrome tanning process which made any show of
practical success, was that patented in 1879 by Heinzerling, which was
acquired in this country by the Eglinton Tanning Company, and also
worked under their license for a short time by the Yorkshire Tanning
Company at Leeds. Though the process was not commercially successful on
any considerable scale, it possesses points of interest which make a
brief description desirable. The hides or skins, after preparation in
the usual way, were treated in a mixed solution of salt, alum (or
aluminium sulphate), and potassium bichromate, but no systematic attempt
was made to reduce the chromic acid to a tanning form, the product
being, at first at least, merely an alum tannage, coloured, and perhaps
somewhat hardened with chromic acid, though on keeping for a length of
time, reduction gradually took place at the expense of the hide-fibre,
and of the fats employed in currying, so that the leather internally
became greyish-green, and really chrome-tanned. Specimens of the early
products of the process, preserved in the museum of the Leather
Industries Department at Leeds, have now all undergone this change, but
are still tough and flexible, showing that the rapid tendering of the
Heinzerling leather, which was one of the causes of its failure, must
have been due to some error in manufacture, and was not inherent in the
process. Interesting, historically, is the fact, that at an early stage
in the life of the patent, a specimen of the leather was submitted to
the late Professor Hummel, in order that he should suggest some means of
overcoming the disagreeable yellow colour of the product. He reduced it
with a bisulphite, and coloured it with an aniline dye, and a piece is
still in the possession of the Yorkshire College, and in perfectly sound
condition. If legal publication of this experiment could have been
Public-domain text, read in full here on John Shaqi.
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