The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
is obtained, when the whole may be made up to one hundred parts, and
will be approximately of the same strength as a 10 per cent. solution
of chrome-alum. A little heat may be needed to start the reaction, but
too much should be avoided, as considerable heat is evolved by the
oxidation; and as much carbonic anhydride is produced, which causes the
solution to effervesce briskly, the vessel used should be of ample size.
In place of cane-sugar, a good quality of glucose may be used, but some
samples contain some impurity which produces a violet solution which
will not tan satisfactorily. This liquor is in regular use in many
tanneries, producing a good quality of chrome calf, but is somewhat
variable in its effects according to the temperature employed in its
preparation, and it appears to have no real advantage over a simple
solution of chrome-alum, rendered basic by soda and with some addition
of salt. A somewhat similar preparation is Eberle’s “chromalin,”[122] in
which some organic substance, probably crude glycerine, is used to
reduce the bichromate. The organic matters, and especially the organic
acids which result from the oxidation of the sugar or glycerine, are not
without influence on the tanning properties of the liquor. Of course
these solutions may be rendered still more basic by the addition of
sodium carbonate. A good stock-liquor, of approximately the same
strength as that above described, is made by dissolving 10 parts of
chrome-alum in 80 parts of tepid, but not hot water,[123] and adding
with constant stirring a solution of 2¹⁄₂ to 3¹⁄₂ parts of washing soda
in 10 parts of water. The chrome alum dissolves somewhat slowly without
the aid of heat, and the solution is best made either in a small drum
driven by power, or by suspending the crystals in a basket near the
surface of the liquor, so that the saturated solution can descend.
[120] Martin Dennis, U.S.A. Pat. 495028, 1893; and 511411, 1893, 7732,
1893. E. Pat. Gallagher.
[121] Leather Trades Review, Jan. 12, 1897.
[122] Compare Eberle’s German patents, 119042, 1898, and 130678, 1899.
The last of these appears to be anticipated, at least as regards the
use of glucose, sugar and starch, by the writer’s publication in 1897
above cited.
[123] Leather Trades Review. Later investigations have shown that the
temperature of the water is unimportant if alkali be added, but
chrome-alum dissociates to some extent in hot water, and comparative
experiments have shown that solutions of the normal salt made with the
aid of heat act on skin as if more acid than those made in the cold.
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